Os resultados indicaram que a pressão interna dos dendritos é a principal responsável pelas fraturas. À medida que crescem, eles exercem uma força que rompe o eletrólito cerâmico, abrindo caminho para curtos-circuitos.
Compreender esse mecanismo é crucial para o desenvolvimento de baterias de estado sólido mais seguras e eficientes. A pesquisa do Instituto Max Planck pode ajudar a criar soluções que impeçam o crescimento dos dendritos ou reforcem o eletrólito contra a pressão interna.
O avanço pode acelerar a chegada de baterias de estado sólido ao mercado, oferecendo dispositivos com maior autonomia e segurança.
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The analysis of internal stresses and plastic deformation showed that there was no lithium accumulation at the tip of the dendrite. Thus, one of the considered mechanisms was discarded.
The results indicated that the hydrostatic stress within the dendrite ultimately causes the brittle fracture of the solid electrolyte. The phenomenon was compared to a continuous jet of water capable of penetrating a rock.
Researchers study ways to avoid failures
The conclusions were also confirmed by phase field simulations and electron backscatter diffraction measurements.
Now, the team is evaluating strategies to delay or prevent the damage. Among them are more resistant electrolytes, microscopic voids that deflect the dendrites, and protective coatings capable of reducing their formation on lithium electrodes.
The study was published in the journal Nature and brings together an interdisciplinary team.
